157 research outputs found
(Z)-4-{1-[(2-Hydroxyethyl)amino]ethylidene}-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one
In the title compound C14H17N3O2, the dihedral angle between the rings is 16.68 (13)°. Although the compound crystallizes in the keto form, the possibility of keto-enamine–enol-imine tautomerism is explained by a strong intramolecular N—H⋯O hydrogen bond
(E)-2-({2-[(E)-(Hydroxyimino)methyl]phenoxy}methyl)-3-p-tolylacrylonitrile
In the title compound, C18H16N2O2, the hydroxyethanimine group is essentially coplanar with the ring to which it is attached (C—C—N—O torsion angle = −176.9°). Molecules are linked into cyclic centrosymmetric R
2
2(6) dimers via O—H⋯N hydrogen bonds
2-Hydroxyethyl 4-hydroxybenzoate
In the title compound, C9H10O4, the dihedral angle between the benzene ring and the –CO2 unit is 11.93 (8)° and the conformation of the 2-hydroxyethyl side chain is gauche [O—C—C—O = −71.91 (17)°]. In the crystal, molecules are linked by O—H⋯O and C—H⋯O hydrogen bonds
Methyl (E)-2-({2-[(E)-(hydroxyimino)methyl]phenoxy}methyl)-3-phenylacrylate
In the title compound, C18H17NO4, the hydroxyethanimine group is essentially coplanar with the ring to which it is attached [C—C—N—O torsion angle = 179.94 (14)°]. The molecules are linked into cyclic centrosymmetric R
2
2(6) dimers via O—H⋯N hydrogen bonds and the crystal packing is further stabilized by C—H⋯O interactions
Diethyl [benzylamino(1,3-diphenyl-1H-pyrazol-4-yl)methyl]phosphonate
In the title compound, C27H30N3O3P, the pyrazole ring is essentially planar [maximum deviation = 0.002 (2) Å] and it forms dihedral angles of 9.3 (1) and 40.2 (1)°, respectively, with the phenyl rings attached to the N and C atoms. In the crystal, pairs of centrosymmetrically related molecules are linked into dimers by N—H⋯O hydrogen bonds
(2E,4E)-Ethyl 5-(phenylsulfonyl)penta-2,4-dienoate
In the title compound, C13H14O4S, both C=C double bonds adopt an E conformation. In the crystal, molecules are linked into centrosymmetric R
2
2(14) dimers via pairs of C—H⋯O hydrogen bonds
3-[(Z)-Benzylidene]-2,3-dihydro-1,5-benzothiazepin-4(5H)-one
In the title compound, C16H13NOS, the seven-membered ring adopts a distorted half-chair conformation. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, forming chains running along the b axis. The crystal packing is further stabilized by C—H⋯O interactions
Diethyl [(2-bromoanilino)(1,3-diphenyl-1H-pyrazol-4-yl)methyl]phosphonate
In the title compound, C26H27BrN3O3P, the central pyrazole ring forms a dihedral angle of 71.7 (2)° with the bromophenyl ring. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R
2
2(10) ring motifs. Four C atoms of the 3-phenyl ring are disordered over two sets of sites [site occupancies = 0.745 (6) and 0.225 (6)]
Ethyl 2-benzyl-3-[3-(4-chlorophenyl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyloctahydropyrrolo[3,4-c]pyrrole-1-carboxylate
The title compound, C37H31ClN4O4, crystallizes with two molecules (A and B) in the asymmetric unit. The pyrrole rings in both molecules are connected via cis fusion, whereas one ring has a twisted conformation and the other assumes a half-chair conformation. In the crystal, the A molecules form inversion dimers via a pair of C—H⋯Cl interactions, while the B molecules form chains propagating in [10], via C—H⋯O interactions. In the crystal, there are also a number of C—H⋯π interactions present
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